Published Paper Details:

Dielectric measurement of a binary mixture of Allyl Bromide with 2-Pentanone and 2-Hexanone was carried out over the entire concentration range using a Time-domain Reflectometer (TDR) at temperatures 293.15K, 303.15K, and 313.15K in microwave frequency range 10 MHz to 10 GHz. The static dielectric constant(?_s) and relaxation time(?) of binary mixture were determined which are further used to study excess static dielectric constant(?_s^E), excess inverse relaxation time??((1/?))?^E, effective Kirkwood correlation factor(geff), and Bruggeman factor(fB). These parameters are used to study intermolecular interaction between Allyl Bromide (ALB) and the carbonyl group of 2-Pentone (2-PE) and 2-Hexanone (2-HE). Intermolecular interaction of Allyl Bromide with 2-Pentanone and 2-Hexanone occurs through dipole-dipole interaction. The excess static dielectric constant and excess inverse relaxation time are fitted to Redlich-Kister equation.