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Paper Title
Role Of Nitrogen Bases In The Oxovanadium(Iv)-Salophen Catalyzed Oxidation Of Phenylsulfinylacetic Acids By Hydrogen Peroxide And The Non-Linear Hammett Correlation
Authors
DR.R.JEEVI ESTHER RATHNAKUMARI, DR.V.VETRISELVI, DR.C.KAVITHA, DR.P.SUBRAMANIAM, DR.J.JANET SYLVIA JABAROSE
Keywords
oxovanadium(IV)-salophen, phenylsulfinylacetic acid, non-linear Hammett, oxidative decarboxylation, nitrogen base
Abstract
The oxidative decarboxylation of phenylsulfinylacetic acid (PSAA) and substituted PSAAs by H2O2 in the presence of oxovanadium(IV)-salophen complex has been studied spectrophotometrically in 100% acetonitrile medium under the influence of nitrogen bases like pyridine (Py), imidazole (ImH) and 1-methylimidazole (MeIm). Kinetic results reveal that the reaction rate is strongly retarded by nitrogen bases and highly sensitive to the nature of base. Among the three nitrogen bases used, MeIm with a strong ?-donating ability shows the highest retarding effect on rate with oxovanadium(IV)-salophen complex. The reaction involving hydroperoxo species and an electrophilic attack of sulfur atom of PSAA on the nucleophilic peroxo oxygen of the vanadium complex is proposed as the mechanistic pathway. The linear Yukawa-Tsuno plot demonstrates that the ground state stabilization of PSAAs through resonance interaction is the cause for the observed non linearity in the Hammett plot.
IJCRT's Publication Details
Unique Identification Number - IJCRT2309650
Paper ID - 244466
Page Number(s) - f343-f354
Pubished in - Volume 11 | Issue 9 | September 2023
DOI (Digital Object Identifier) - http://doi.one/10.1729/Journal.37753
Publisher Name - IJCRT | www.ijcrt.org | ISSN : 2320-2882
E-ISSN Number - 2320-2882
Cite this article
DR.R.JEEVI ESTHER RATHNAKUMARI, DR.V.VETRISELVI, DR.C.KAVITHA, DR.P.SUBRAMANIAM, DR.J.JANET SYLVIA JABAROSE, "Role Of Nitrogen Bases In The Oxovanadium(Iv)-Salophen Catalyzed Oxidation Of Phenylsulfinylacetic Acids By Hydrogen Peroxide And The Non-Linear Hammett Correlation", International Journal of Creative Research Thoughts (IJCRT), ISSN:2320-2882, Volume.11, Issue 9, pp.f343-f354, September 2023, Available at :http://www.ijcrt.org/papers/IJCRT2309650.pdf
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Submit Manuscript Online Impact Factor: 7.97 Review Results : Within 02-03 Days Paper Publication : Within 02-03 Days
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ISSN: 2320-2882 Impact Factor: 7.97 and ISSN APPROVED Journal Starting Year (ESTD) : 2013
ISSN and 7.97 Impact Factor Details
ISSN: 2320-2882 Impact Factor: 7.97 and ISSN APPROVED Journal Starting Year (ESTD) : 2013
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