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Paper Title
SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF PLATINUM( II) WITH BIDENTATE SCHIFF BASE LIGANDS
Authors
Aniket Verma, Dr. Shamshad Ahmad Khan
Keywords
Pyridine-2-carbaldehyde, 2,6-diacetyl pyridine, Pt-salt, 2-aminopyrazine, semicarbazide
Abstract
A novel series of platinum (II) complexes derived from Schiff base ligands 2-(pyridine-2?-carboxaldehydeimino) pyrazine and 2,6-diacetyl pyridine bis (semicarbazone) have been synthesized and characterizes by micro elemental analysis, molar conductivity, magnetic susceptibility, FTIR, and electronic absorption spectra. The Pt (II) complexes are colored and stable in air. In the metal complexes the metal -ligand ratio found to be 1:2. The higher molar conductivity data of the complexes in DMF solution indicates they are electrolytic in nature. The spectral data indicate that the Schiff base ligand behaves as bidentate and coordinated with metal ion by azomethine nitrogen, pyridine nitrogen atom and oxygen atom of semicarbazone to the metal ion. On the basis of elemental analysis, magnetic susceptibility and electronic spectral data, geometry of complexes was proposed to be square planar in nature.
IJCRT's Publication Details
Unique Identification Number - IJCRT1134137
Paper ID - 210995
Page Number(s) - 816-821
Pubished in - Volume 5 | Issue 4 | October 2017
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Publisher Name - IJCRT | www.ijcrt.org | ISSN : 2320-2882
E-ISSN Number - 2320-2882
Cite this article
Aniket Verma, Dr. Shamshad Ahmad Khan, "SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF PLATINUM( II) WITH BIDENTATE SCHIFF BASE LIGANDS", International Journal of Creative Research Thoughts (IJCRT), ISSN:2320-2882, Volume.5, Issue 4, pp.816-821, October 2017, Available at :http://www.ijcrt.org/papers/IJCRT1134137.pdf
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ISSN: 2320-2882 Impact Factor: 7.97 and ISSN APPROVED Journal Starting Year (ESTD) : 2013
ISSN and 7.97 Impact Factor Details
ISSN: 2320-2882 Impact Factor: 7.97 and ISSN APPROVED Journal Starting Year (ESTD) : 2013
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