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  Published Paper Details:

  Paper Title

Kinetic of Formic acid inhibited uncatalysed and CoO catalysed autoxidation of S(IV) in alkaline Medium

  Authors

  Anil Kumar,  Himanshu Sharma,  D.S.N. Prasad

  Keywords

Kinetics; Autoxidation; SO2; CoO ; Catalysis; Inhibition ; formic acid, free radical mechanism

  Abstract


The kinetics of the formic acid inhibited CoO catalysed autoxidation of S(IV) in alkaline medium has been studied and based on the observed results following rate has been proposed. Rate constants and the order of reaction were calculated and the reaction was found to be pseudo- first order in all cases. The effect of pH and temperature are also discussed. The value of apparent activation (Ea) energy was calculated by Arrhenius equation. On the basis of inhibition parameters, the reaction follows free radical mechanism.

  IJCRT's Publication Details

  Unique Identification Number - IJCRT2312159

  Paper ID - 247389

  Page Number(s) - b378-b388

  Pubished in - Volume 11 | Issue 12 | December 2023

  DOI (Digital Object Identifier) -    http://doi.one/10.1729/Journal.37032

  Publisher Name - IJCRT | www.ijcrt.org | ISSN : 2320-2882

  E-ISSN Number - 2320-2882

  Cite this article

  Anil Kumar,  Himanshu Sharma,  D.S.N. Prasad,   "Kinetic of Formic acid inhibited uncatalysed and CoO catalysed autoxidation of S(IV) in alkaline Medium", International Journal of Creative Research Thoughts (IJCRT), ISSN:2320-2882, Volume.11, Issue 12, pp.b378-b388, December 2023, Available at :http://www.ijcrt.org/papers/IJCRT2312159.pdf

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ISSN: 2320-2882
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Journal Starting Year (ESTD) : 2013
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ISSN and 7.97 Impact Factor Details


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ISSN
ISSN: 2320-2882
Impact Factor: 7.97 and ISSN APPROVED
Journal Starting Year (ESTD) : 2013
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