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INTERNATIONAL JOURNAL OF CREATIVE RESEARCH THOUGHTS - IJCRT (IJCRT.ORG)
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ISSN Approved Journal No: 2320-2882 | Impact factor: 7.97 | ESTD Year: 2013
Call For Paper - Volume 12 | Issue 5 | Month- May 2024
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Paper Title
SYNTHESIS AND SPECTRAL CHARACTERIZATION OF BINUCLEAR COMPOUND OF CU(II) AND NI(II) SCHIFF BASE OF 2-HYDROXY-5 -METHYLACETOPHENONE AND 1,2-PROPYLENEDIAMINE WITH ALKALI METAL SALTS OF DINITROPHENOL
Authors
CHANDAN KUMAR, RABINDRA KUMAR DEO
Keywords
2-hydroxy-5-methylacetophenone, Schiff base, propylenediamine, alkali metal complexes, IR, UV-Visible
Abstract
A series of novel binuclear complexes of general formula MaMAPD.MbL were synthesized by interaction of stable CuII and NiII metal chelate of Schiff base derived from propylenediamine and 2-hydroxy-5-methylacetophenone with alkali metal salts of organic acids such as 2,4-dinitrophenol. The structure of heterobinuclear alkali metal complexes were discussed on the basis of elemental analysis, IR spectra, UV-Vis spectra and magnetic measurement. The low value of conductivity measurement of the complexes shows that non-electrolytic nature. The IR spectral studies were suggested that the CuII and NiII metal chelate act as ligand and coordination towards alkali metal salts takes place through phenolic oxygen atom. Binuclear nickel(II) or copper(II) complex of Schiff base have square planar geometry. There are no change in the stereochemistry of the Ni2+ and Cu2+ in adducts with their metal chelate.
IJCRT's Publication Details
Unique Identification Number - IJCRT2302414
Paper ID - 231347
Page Number(s) - d401-d404
Pubished in - Volume 11 | Issue 2 | February 2023
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Publisher Name - IJCRT | www.ijcrt.org | ISSN : 2320-2882
E-ISSN Number - 2320-2882
Cite this article
CHANDAN KUMAR, RABINDRA KUMAR DEO, "SYNTHESIS AND SPECTRAL CHARACTERIZATION OF BINUCLEAR COMPOUND OF CU(II) AND NI(II) SCHIFF BASE OF 2-HYDROXY-5 -METHYLACETOPHENONE AND 1,2-PROPYLENEDIAMINE WITH ALKALI METAL SALTS OF DINITROPHENOL", International Journal of Creative Research Thoughts (IJCRT), ISSN:2320-2882, Volume.11, Issue 2, pp.d401-d404, February 2023, Available at :http://www.ijcrt.org/papers/IJCRT2302414.pdf
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ISSN: 2320-2882 Impact Factor: 7.97 and ISSN APPROVED Journal Starting Year (ESTD) : 2013
ISSN and 7.97 Impact Factor Details
ISSN: 2320-2882 Impact Factor: 7.97 and ISSN APPROVED Journal Starting Year (ESTD) : 2013
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